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Creators/Authors contains: "Buytendyk, Allyson M."

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  1. ; ; ; ; ; ; ( , Physical Chemistry Chemical Physics)
    Quadrupole-bound anions are negative ions in which their excess electrons are loosely bound by long-range electron-quadrupole attractions. Experimental evidence for quadrupole-bound anions has been scarce; until now, only trans -succinonitrile had been experimentally confirmed to form a quadrupole-bound anion. In this study, we present experimental evidence for a new quadrupole-bound anion. Our combined Rydberg electron transfer/anion photoelectron spectroscopy study demonstrates that the ee conformer of 1,4-dicyanocyclohexane (DCCH) supports a quadrupole-bound anion state, and that the cis -DCCH conformer forms a dipole-bound anion state. The electron binding energies of the quadrupole- and dipole-bound anions are measured as 18 and 115 meV, respectively, both of which are in excellent agreement with theoretical calculations by Sommerfeld. 
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  2. ; ; ; ; ( , The Journal of Chemical Physics)
  3. ; ; ; ; ( , The Journal of Chemical Physics)
  4. ; ; ; ; ( , The Journal of Chemical Physics)
  5. ; ; ; ; ( , The Journal of Chemical Physics)